For personal protection see section 8. If dry, it can be charged electrostatically by swirling, pneumatic transport, pouring, etc.FORMALDEHYDE (ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S.) c. Treat metabolic acidosis with sodium bicarbonate. 10-20 ppm, breathing difficult, cough, severe burning of nose and throat. (ERG, 2016), Behavior in Fire: Changes to formaldehyde gas, which is highly flammable. Rinse skin with water [or shower]. Formaldehyde solution ACS reagent, 37 wt. Regulation: CHIP, 67/548/EEC <> Page 5 of 10 MSDS ± FORMALDEHYDE respirator with a formaldehyde cartridge may be worn up to 50 times the exposure lim it or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. Our experts will walk you through compliance in a consultation session, to fast-track the population of your SDS library, removing all the work from you allowing you to get on with your job. May generate toxic formaldehyde gas when heated. Now the time has come to put your hand in your pocket and help us to maintain this wonderful solution. If leak or spill has not ignited, use water spray to disperse vapors, and to protect men attempting to stop leak. Skin -- primary irritation from strong solutions, gas. Hazardous polymerization may occur. Hazard Identification Very hazardous in case of eye contact (irritant), of ingestion, . According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is low(SRC). You’ll be redirected to the banking site to complete your payment. Ensure adequate ventilation. The human genome contains several non-transcribed pseudogenes related to this gene. P403+P233 Store in a well-ventilated place. Wear impervious clothing. Contact with substance may cause severe burns to skin and eyes. Use fluorocarbon water spray, Cellosize and Hycar to diminish vapors. Treat coma and shock if they occur. Avoid breathing vapours, mist or gas. H317 May cause an allergic skin reaction. P310 Immediately call a POISON CENTER/doctor/\u2026. %PDF-1.5 Avoid oxidizing and alkaline materials. (EPA, 1998), Excerpt from ERG Guide 132 [Flammable Liquids - Corrosive]: May cause toxic effects if inhaled or ingested/swallowed. Maintain open airway and assist ventilation if necessary. In people sensitized to formaldehyde, late asthmatic reactions may be provoked by brief exposures at approximately 3 ppm. The ‘Substance identity’ section is calculated from substance identification information from all ECHA databases. Remove contact lenses, if present and easy to do. Emergency and supportive measures: 1. 50-100 ppm, acute irritation of respiratory tract, very serious injury likely. Evacuate personnel to safe areas. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. /Formaldehyde/ /Formalin (as formaldehyde)/. Avoid formation of dust and aerosols. Acute -- below 1 ppm, odor perceptible to most. Particularly relevant to the discussions regarding sufficient evidence was a recent study accepted for publication which, for the first time, reported aneuploidy in blood of exposed workers characteristic of myeloid leukaemia and myelodysplastic syndromes, with supporting information suggesting a decrease in the major circulating blood-cell types and in circulating haematological precursor cells. Handle in accordance with good industrial hygiene and safety practice. Refer immediately for medical attention. H335 May cause respiratory irritation. Avoid breathing dust. We'll also keep your SDS up-to-date for you. Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: Some may burn but none ignite readily. This enzyme is an important component of cellular metabolism for the elimination of formaldehyde, a potent irritant and sensitizing agent that causes lacrymation, rhinitis, pharyngitis, and contact dermatitis. 13. CAS Numbers: ,50-00-0,67-56-1 P202 Do not handle until all safety precautions have been read and understood. Commercial formaldehyde-alcohol solutions are stable. Experiments performed on a variety of fish and shrimp showed no bioconcentration of formaldehyde(4,5). Use water spray, dry chemical, alcohol foam, or carbon dioxide. P280 Wear protective gloves/protective clothing/eye protection/face protection. 3. Runoff to sewer may create fire or explosion hazard. (USCG, 1999). endobj Avoid contact with skin and eyes. Vapor explosion hazard indoors, outdoors or in sewers. /Pure formaldehyde/, Lower flammable limit: 7.0% by volume; Upper flammable limit: 73% by volume, In water:soluble, > 100\u2009g/100 ml\uff0820\u2009\u00b0C\uff09, ADR/RID: FORMALDEHYDE SOLUTION\nwith not less than 25% formaldehyde, IMDG: FORMALDEHYDE SOLUTION\nwith not less than 25% formaldehyde, IATA: FORMALDEHYDE SOLUTION\nwith not less than 25% formaldehyde, Oral: LD50 Rat oral 100 mg/kg /SRP: percent solution not specified/, Inhalation: LC50 Rat inhalation 0.82 mg/L (1/2 hour), Dermal: LD50 Rabbit percutaneous 270 mg/kg /Formalin/, Toxicity to fish: LC50; Species: Oncorhynchus mykiss (Rainbow trout) weight 0.63 g; Conditions: static; Concentration: 118 ppm for 96 hr (95% confidence limit: 99.7-140 ppm) /37% AI formulated product, Toxicity to daphnia and other aquatic invertebrates: EC50; Species: Daphnia magna (Water Flea) age <24 hr; Conditions: freshwater, static; Concentration: 14600 ug/L for 48 hr (95% confidence interval: 11300-18000 ug/L); Effect: intoxication, immobilization /37% purity, Toxicity to algae: EC50; Species: Scenedesmus subspicatus (Green Algae); Conditions: freshwater, static; Concentration: 211000 ug/L for 49-79 min; Effect: population, decreased photosynthesis /formulation, Toxicity to microorganisms: no data available, ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road, RID: Regulation concerning the International Carriage of Dangerous Goods by Rail, IMDG: International Maritime Dangerous Goods, IATA: International Air Transportation Association, IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home, HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm, IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/, eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en, CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple, ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp, ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg, Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp, ECHA - European Chemicals Agency, website: https://echa.europa.eu/.
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